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Bleach is the generic name for any chemical product that is used industrially or domestically to remove color (whitening) from a fabric or fiber or to clean or to remove stains in a process called bleaching. It often refers specifically to a dilute solution of sodium hypochlorite, also called "liquid bleach".
Many bleaches have broad spectrum bactericidal properties, making them useful for disinfecting and sterilizing. They are used in swimming pool sanitation to control bacteria, viruses, and algae, and in many places where sterile conditions are required. They are also used in many industrial processes, notably in the bleaching of wood pulp. Bleaches also have other minor uses like removing mildew, killing weeds, and increasing the longevity of cut flowers.
Bleaches work by reacting with many colored organic compounds, such as natural pigments, and turning them into colorless ones. While most bleaches are oxidizing agents (chemicals that can remove electrons from other molecules), some are reducing agents (that donate electrons).
Chlorine, a powerful oxidizer, is the active agent in many household bleaches. Since pure chlorine is a toxic corrosive gas, these products usually contain hypochlorite, which releases chlorine. "Bleaching powder" usually means a formulation containing calcium hypochlorite.
Oxidizing bleaching agents that do not contain chlorine are usually based on peroxides such as hydrogen peroxide, sodium percarbonate, and sodium perborate. These bleaches are called "non-chlorine bleach", "oxygen bleach", or "color-safe bleach".
The earliest form of bleaching involved spreading fabrics and cloth out in a bleachfield to be whitened by the action of the sun and water. In the 17th century, there was a significant cloth bleaching industry in Western Europe, using alternating alkaline baths (generally lye) and acid baths (such as lactic acid from sour milk, and later diluted sulfuric acid). The whole process lasted up to six months.
Chlorine-based bleaches, which shortened that process from months to hours, were invented in Europe in the late 18th century. Swedish chemist Carl Wilhelm Scheele discovered chlorine in 1774, and in 1785 French scientist Claude Berthollet recognized that it could be used to bleach fabrics. Berthollet also discovered sodium hypochlorite, which became the first commercial bleach, named Eau de Javel ("Javel water") after the borough of Javel, near Paris, where it was produced.
Scottish chemist and industrialist Charles Tennant proposed in 1798 a solution of calcium hypochlorite as an alternative for Javel water, and patented bleaching powder (solid calcium hypochlorite) in 1799. Around 1820, French chemist Antoine Germain Labarraque discovered the disinfecting and deodorizing ability of hypochlorites, and was instrumental in popularizing their use for such purpose. His work greatly improved medical practice, public health, and the sanitary conditions in hospitals, slaughterhouses, and all industries dealing with animal products.
Louis Jacques Thénard first produced hydrogen peroxide in 1818 by reacting barium peroxide with nitric acid. Hydrogen peroxide was first used for bleaching in 1882, but did not become commercially important until after 1930. Sodium perborate as a laundry bleach has been used in Europe since the early twentieth century, and became popular in North America in the 1980s.
Sunlight acts as a bleach through a process leading to similar results: high energy photons of light, often in the violet or ultraviolet range, can disrupt the bonds in the chromophore, rendering the resulting substance colorless. Extended exposure often leads to massive discoloration usually reducing the colors to white and typically very faded blue.
The broad-spectrum effectiveness of most bleaches is due to their general chemical reactivity against organic compounds, rather than the selective inhibitory or toxic actions of antibiotics. They irreversibly denature or destroy many proteins, making them extremely versatile disinfectants.
Hypochlorite bleaches in low concentration were also found to attack bacteria by interfering with heat shock proteins on their walls. According to 2013 Home Hygiene and Health report, using bleach, whether chlorine- or peroxide-based, significantly increases germicidal efficiency of laundry even at low temperatures (30-40 degrees Celsius), which makes it possible to eliminate viruses, bacteria and fungi from variety of clothing in home setting.
Sodium dithionite (also known as sodium hydrosulfite) is one of the most important reductive bleaching agents. It is a white crystalline powder with a weak sulfurous odor. It can be obtained by reacting sodium bisulfite with zinc
In Reversal processing, residual silver in the emulsion after the first development is reduced to a soluble silver salt using a chemical bleach, most commonly EDTA. A conventional fixer then dissolves the reduced silver but leaving the unexposed silver halide intact. This unexposed halide is then exposed to light or is chemically treated so that a second development produces a positive image. In colour and chromogenic film, this also generates a dye image in proportion to the silver.
Photographic bleaches are also used in black-and-white photography to selectively reduce silver to reduce silver density in negatives or prints. In such cases the bleach composition is typically an acid solution of potassium dichromate.
Industrial bleaching agents can be sources of concern. For example, the use of elemental chlorine in the bleaching of wood pulp produces organochlorines and persistent organic pollutants, including dioxins. According to an industry group, the use of chlorine dioxide in these processes has reduced the dioxin generation to under detectable levels. However, respiratory risk from chlorine and highly toxic chlorinated byproducts still exists.
The significant increases observed in indoor air concentrations of several chlorinated VOCs (especially carbon tetrachloride and chloroform) indicate that the bleach use may be a source that could be important in terms of inhalation exposure to these compounds. While the authors suggested that using these cleaning products may significantly increase the cancer risk, this conclusion appears to be hypothetical:
US Government regulations (21 CFR 178 Subpart C) allow food processing equipment and food contact surfaces to be sanitized with solutions containing bleach, provided that the solution is allowed to drain adequately before contact with food, and that the solutions do not exceed 200 parts per million (ppm) available chlorine (for example, one tablespoon of typical household bleach containing 5.25% sodium hypochlorite, per gallon of water).
A 1-in-47 dilution of household bleach with water (1 part bleach to 47 parts water) is effective against many bacteria and some viruses in homes. Even "scientific-grade", commercially produced disinfection solutions such as Virocidin-X usually have sodium hypochlorite as their sole active ingredient, though they also contain surfactants (to prevent beading) and fragrances (to conceal the bleach smell).
Color safe bleach is a chemical that uses hydrogen peroxide as the active ingredient (to help remove stains) rather than sodium hypochlorite or chlorine. It also has chemicals in it that help brighten colors. Hydrogen peroxide is also used for sterilization purposes and water treatment, but its disinfectant capabilities may be limited due to the concentration in the colorsafe bleach solution as compared to other applications.
The safety of bleaches depends on the compounds present, and their concentration. Generally speaking, the ingestion of bleaches will cause damage to the esophagus and stomach, possibly leading to death. On contact with the skin or eyes, it causes irritation, drying, and potentially burns. Inhalation of bleach fumes can damage the lungs. Personal protective equipment should always be used when using bleach.
Bleach should never be mixed with vinegar or other acids, as this will create highly toxic chlorine gas, which can cause severe burns internally and externally. Mixing bleach with ammonia similarly produces toxic chloramine gas, which can burn the lungs. Mixing bleach with hydrogen peroxide results in an exothermic chemical reaction that releases oxygen, and may cause the contents to splatter and cause skin and eye injury. Heating bleach and boiling it may produce chlorates, strong oxidizers which may lead to a fire or explosion.
Miracle Mineral Supplement (MMS), also promoted as "Master Mineral Solution" or "Chlorine Dioxide Solution" or CDS, to evade restrictions by online retail platforms, is a bleach solution that has been fraudulently promoted as a cure-all since 2006. Its main active ingredient is sodium chlorite, which is "activated" with citric acid to form chlorine dioxide. In an attempt to evade health regulations, its inventor, former Scientologist, Jim Humble, formed the Genesis II Church of Health and Healing, a fake religion whose "sacrament" is MMS.
During the COVID-19 pandemic advocates of MMS, such as QAnon proponent Jordan Sather and Mark Grenon, who are affiliated with the Genesis II Church, began to suggest this would treat COVID-19. Several sources interpreted remarks by U.S. President Trump, in a 23 April 2020 briefing, as promoting this claim, leading the CDC, scientists, and bleach companies to re-state that bleach is harmful to humans and should not be ingested or injected. MSN News quoted Professor Rob Chilcott, a toxicology expert from the University of Hertfordshire, that there is no scientific evidence that injected bleach or disinfectants will affect viral particles, but that injecting bleach would "likely result in significant, irreversible harm and probably a very unpleasant death." 781b155fdc